Pillar[5]arenes with an introverted amino group: a hydrogen bonding tuning effect.
نویسندگان
چکیده
Pillar[5]arenes with introverted amino groups were produced through aminolysis. X-ray analysis demonstrated that the intramolecular hydrogen bonding induced the amino group toward the inner space of the cavity. The kinetic studies and molecular modelings revealed that the hydrogen bonding also contributed to the acceleration of the aminolysis through stabilizing the intermediate.
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 11 2 شماره
صفحات -
تاریخ انتشار 2013